The pyrrole, Fe2O3, and Fe2O3/Pyrrole composites was synthesized by a simple hydrothermal method. The morphological characterizations (FE-SEM) indicated the Fe2O3covered by Pyrrolenanosheets. Optical features of the synthesized samples were examined by XRD, FTIR, and SEM The catalytic efficacy of methylene blue dye degradation is 93.4 % in 100 min, it is higher than that of pristine Pyrrole(40%) and Fe2O3 (72%). Fe2O3/PPy composite shows outstanding catalytic steadiness and efficiency, it still maintains the catalytic efficiency. The catalytic enhancement due to the high specific surface area of Pyrrole, and also the composite shows high reliability and degradation efficiency. Theprepared material is a potential candidate for high performance energy storage and photocatalytic applications