This is study of the unsteady first order chemical reaction effects on radiative flow past a uniformly accelerated isothermal infinite vertical plate with radiation and uniform mass diffusion with heat source and surface temperature are investigated. The governing nonlinear partial differential equations have been reduced to the coupled nonlinear ordinary differential equations by using perturbation technique. The influence of the various interesting parameters on the flow velocity, temperature and concentration discussed through graphs in detailed. This model finds applications in solar energy collection systems, geophysics and astrophysics, aero space and also in the design of high temperature chemical process systems.